- Engineered barrier system of deep geological repositories
- Gas transport in sealing materials
- Natural barriers (argillaceous rocks, marls)
- Physical and hydraulic characterisation of concrete
- Physical and hydraulic characterisation of soils and liners
In this field the group works among others in these topics:
- Effect of salinity and temperature on the properties and behaviour of sealing materials.
- Hydro-mechanical behaviour of unsaturated geological materials (soils).
- Bentonite microstructural changes driven by hydration.
The boost to this core line was the ENRESA’s project FEBEX, financed also by the European Commission and with a large international participation. This project included a large-scale demonstration test of the near field of a deep geological repository (DGR) under natural conditions. The FEBEX in situ test was completely dismantled in 2015, after 18 years of operation, in the framework of the FEBEX-DP project. The group led the sampling and postmortem characterisation works (http://www.ciemat.es/portal.do?IDM=61&NM=2&identificador=1313). So far, this is the longest such in situ test ever dismantled, hence it is of outstanding interest for the scientific community working in the DGR field.
As part of the FEBEX project a large-scale mock-up test was installed at CIEMAT facilities to simulate the bentonite engineered barrier of a DGR. It is in operation since 1997
Related projects:
- CAMBAR-2 (2022-2026)
- CAMBAR (2016-2019) Convenio Marco CIEMAT /ENRESA 2/6/2004. Anexo XLII.
- FEBEX-DP (2014-2018)
- PEBS (2010-2014)
- FEBEX-E (2008-2013)
- NF-PRO (2004-2007)
- RESEAL I (1996-1999) and II (2000-2005)
- FEBEX I (1995-1999) and II (2000-2003)
Currently we are paying particular attention to the following aspects inside this research area:
- Long-term behaviour of sealing materials
In the DGR context “long-term” means “close-to-saturation conditions”, that is, following the first transient stage during which the saturation of the barrier takes place under a significant thermal gradient. In the course of the barrier saturation its properties are affected by the changes in water content and dry density that take place as a result of heating and hydration. Until now neither the large-scale nor the laboratory tests have provided conclusive evidence about the reversibility of these changes occurred in the barrier. This is why the European project BEACON (2017-2021) analyses the long-term mechanical evolution of the bentonite barrier.
- Effect of temperature >100°C in bentonite-based barriers
The effect of temperatures higher than 100°C on barrier materials has been addressed in the last years because, if higher temperatures could be tolerated in a repository, it would be more effective on economic terms. This is one of the topics dealt with by the European Union inside Horizon2020, and the group is currently participating in the project EURAD-HITEC (Influence of temperature on clay-based material behaviour, 2019-2023).
- Mineralogical alteration of bentonites
The project MINALBEN (Experimental and modelling study of MINeralogical ALteration of BENtonites, 2016-2024) studies the geochemical behaviour and the mineralogical alteration of bentonite tested in thermo-hydraulic cells and their modelling. It is therefore an experimental and theoretical research carried out through a contract between CIEMAT and AMPHOS-21, whose end user is POSIVA, the Finnish nuclear waste management agency.
This research line started in 1997 in the framework of the projects GASBEN and GMT, but it mainly developed from 2009 as a result of the participation of the group in the UE project FORGE. Among the group facilities there is a laboratory for gas transport studies (more information in "Facilities and Laboratories --> Gas transport laboratory") where sealing materials (bentonite and its mixtures with other materials), shales and concrete are tested. A doctoral thesis perfomed in the group about gas transport in barrier materials was awarded Extraordinary PhD Prize of the Faculty of Geology of the Universidad Complutense de Madrid in 2019 (http://www.ciemat.es/cargarAplicacionNoticias.do?texto=tesis&idArea=0&identificador=1631).
Currently the group is participating in the EURATOM 2020 project EURAD-GAS about the mechanicistic understanding of gas migration.
Related projects:
- EURAD-GAS (2019-2024) https://www.ejp-eurad.eu/implementation/mechanistic-understanding-gas-transport-clay-materials-gas
- FORGE (2009-2013) https://cordis.europa.eu/project/id/230357
- GMT (1999-2000) https://www.grimsel.com/gts-phase-v/gmt/gmt-laboratory-programme/gmt-initial-tests-
- GASBEN (1997-1999)
We are acting as international collaborators of the project “Impact of Coupled Gas Migration and Thermo-Hydro-Mechanical Processes on the Performance of Repositories for High Level Nuclear Waste” of the Texas A&M University, financed by the Departament of Energy of USA. https://sites.google.com/view/doe-project/home-page
Natural barriers have been studied from two points of view:
- As host rock in which the DGR is excavated, characterising its physical, hydraulic and mechanical properties as a function of depth in Spanish clay formations (Duero and Ebro basins) and other claystones (Opalinus clay, Switzerland).
- As foundation rock for a Centralised Temporary Storage (Almacenamiento Temporal Centralizado, ATC, https://www.enresa.es/eng/index/activities-and-projects/high-level-waste).
Related projects:
Concrete (and concrete-related materials) can also be a barrier agains the migration of contaminants, and as such it is used in El Cabril disposal facility (https://www.enresa.es/eng/index/activities-and-projects/el-cabril), where the waste packages received are left in concrete casks. When a cask is at full capacity, it is immobilised by means of injected mortar, forming a compact block. This block is deposited in the disposal vault. Once the disposal vault is full, it is sealed with a slab made of reinforced concrete and waterproofed. Techniques have been developed for the determination of hydraulic conductivity, unsaturated permeability (by back-analysis of evaporation test in concrete columns, and water retention curves. Recently we have performed the characterisation of concrete used by the Swedish agency for nuclear waste (SKB).
Related projects:
- Caracterización de materiales de cobertera y de confinamiento de base hormigón (2006-2009, 2009-2013)
- FORGE (2010-2013)
A system has been developed to determine the unsaturated permeability of soils by means of evaporation/infiltration tests, which has been used for the study of the hydraulic properties of cover materials (drainage and waterproofing layers) used in El Cabril disposal facility for very low, low and intermediate-level radioactive waste.
Related projects:
- Suelos y acuíferos de Aznalcóllar (1998-1999, 1999-2000)
- Caracterización de materiales de cobertera (2006-2009, 2009-2013)